A thermoluminescent dosimeter, or TLD, is a type of radiation dosimeter. A TLD measures ionizing radiation exposure by measuring the amount of visible light emitted from a crystal in the detector when the crystal is heated. The amount of light emitted is dependent upon the radiation exposure. Materials exhibiting thermoluminescence in response to ionizing radiation include but are not limited to calcium fluoride, lithium fluoride, calcium sulfate, lithium borate, calcium borate, potassium bromide and feldspar.
The two most common types of TLDs are calcium fluoride and lithium fluoride, with one or more impurities to produce trap states for energetic electrons. The former is used to record gamma exposure, the latter for gamma and neutron exposure (indirectly, using the Li-6 (n,alpha) nuclear reaction; for this reason, LiF dosimeters may be enriched in lithium-6 to enhance this effect or enriched in lithium-7 to reduce it). As the radiation interacts with the crystal it causes electrons in the crystal's atoms to jump to higher energy states, where they stay trapped due to intentionally introduced impurities (usually manganese or magnesium)[1] in the crystal, until heated. Heating the crystal causes the electrons to drop back to their ground state, releasing a photon of energy equal to the energy difference between the trap state and the ground state. The electrons can also drop back to ground state after a long period of time; this effect is called fading and is dependent on the incident radiation energy and intrinsic properties of the TLD material. As a result, each material possesses a limited shelf life after which dosimetric information can no longer be obtained. This varies from several weeks in calcium fluoride to up to two years for lithium fluoride.
It can be used both for environmental monitoring and for staff personnel in facilities involving radiation exposure, among other applications.